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姓 名 涂正凯(研究员) 性 别
职 称 研究员 毕业学校 华中科技大学
个人主页
联系方式 15102756731
邮 箱 tzklq@hust.edu.cn
通讯地址 华中科技大学能源与动力工程学院609室 430074
个人资料简介
涂正凯,男,研究员,2016年度湖北省杰出青年基金获得者,主要从事燃料电池、制氢以及储能方面的研究。2009年博士毕业于华中科技大学能源与动力工程学院,同年进入武汉理工大学材料复合新技术国家重点实验室工作,2016年晋升为正高。期间在新加坡南洋理工大学从事访问学者研究工作。2017年8月进入华中科技大学能源与动力工程学院工作。目前已发表论文70余篇,获得发明专利5项,出版专著1部。主持了国家自然科学基金面上项目2项,装备预研教育部联合基金1项,湖北省杰出青年基金1项,中国博士后科学基金1项,并以骨干参与并完成了多项863重大项目。主要学术贡献:(1)提出高温低阻的氢-空燃料电池设计原则。设计具有自对称的流场结构的燃料电池,开发出国内第一台具有多项知识产权的高温质子交换膜燃料电池系统样机。该研究的完成填补了国内质子交换膜燃料电池热电联供技术的空白,可解决家庭住宅、小区乃至大型建筑的热、电联供问题。研究成果发表在J Power Sources (2013) 上,目前已引用37次,入选2014,2015年度ESI高被引论文。(2)提出重力辅助排水的氢氧燃料电池设计机理。利用相变冷凝以及重力辅助排水技术,研发出全闭口运行的氢氧质子交换膜燃料电池(氢气、氧气利用率达到100%)。该电池的研发成功,突破了国外的技术封锁,使大功率的氢氧燃料电池发动机作为水下潜航器的主动力成为可能。研究成果发表在Applied Energy(2013)上,目前已他引22次。已与上汽,712等国内多家燃料电池企业建立实质性合作关系,并担任多家燃料电池企业技术顾问。
热诚欢迎热爱燃料电池、制氢及储能方向的博士或博士后加入本课题组!

教育及工作经历

    2004/09-2009/06,华中科技大学,能源与动力工程学院,博士
    2000/09-2004/06,华中科技大学,环境科学与工程学院,学士
    研究工作经历(按时间倒排序)
    2017/08-至今,   华中科技大学,能源与动力工程学院,研究员
    2016/09-至今,   新加坡南洋理工大学,高级访问学者
    2016/09-2017/08,武汉理工大学,材料复合新技术国家重点实验室,研究员
    2015/05-2016/04,新加坡南洋理工大学,访问学者
    2011/09-2016/09,武汉理工大学,材料复合新技术国家重点实验室,副研究员
    2009/09-2011/09,武汉理工大学,材料复合新技术国家重点实验室,博士后

研究方向

    主要从事燃料电池、制氢以及储能方面的研究。

科研项目

    主持或参与的项目:
    (1)    主持:国家自然科学基金面上项目:潜器用燃料电池重力辅助排水机制的理论分析与实验研究(项目编号:51476119),2015-2018
    (2)    主持:国家自然科学基金面上项目:氢氧燃料电池脉冲排放过程水分脱离与再生行为的理论分析与实验研究(项目编号:51776144),2018-2021
    (3)    主持:装备预研教育部联合基金项目:移动式深海装备用燃料电池动力系统关键技术,2017-2019
    (4)    主持:湖北省杰出青年科学基金:燃料电池水淹过程碳腐蚀行为的动力学机制研究(项目编号:2016CFA041),2016-2018
    (5)    主持:“质子交换膜燃料电池内的传质流动的机理研究” ,中国博士后科学基金(20100471165),2010-2012;
    (6)    主持:企业委托项目:7kW级燃料电池研制(项目编号:20131h0302),2013-2014
    (7)    主持:企业委托项目:6kW级燃料电池研制与性能考评,2014-2015
    (8)    执行:“高温质子交换膜电极、电池堆技术的研发及其综合评估”, 国家“863”重点项目(2008AA050403),经费:723万
    (9)    参与:“燃料电池电堆及关键材料研制开发”,863重大课题 (2008AA11A106),经费:1217万
    (10)    参与:“燃料电池低成本膜电极组件/双极板及电堆制备技术研究” ,863主题课题(2013AA110201),经费:540万
    (11)    参与:“车用燃料电池电堆及膜电极关键技术” ,863重大课题(2012AA110601),经费:1390万

代表性论文与专利

    主要论著:
    2017
    (1)    涂正凯,余意。质子交换膜燃料电池水热管理技术基础及应用,科学出版社,2017.
    (2)    B. Chen, Y.H. Cai, Z..K. Tu*, S.H. Chan, J. Wang, Y. Yu. Gas purging effect on the degradation characteristic of a proton exchange membrane fuel cell with dead-ended mode operation I. With Different electrolytes, Energy, 2017 (Doi:10.1016/j.energy.2017.09.067)
    (3)    H.W. Chang, Z.M. Wan*, Y. Zheng, X. Chen, S.M. Shu, Z.K. Tu*, S.H. Chan, R. Chen, X.D. Wang. Energy and exergy based working fluid selection and performance analysis of a high-temperature PEMFC-based micro combined cooling heating and power system. Applied Energy, 2017, 204: 446-458.
    (4)    B. Chen, Y.H. Cai, Y. Yu, J. Wang, Z.K. Tu*, S. H. Chan. Gas purging effect on the degradation characteristic of a proton exchange membrane fuel cell with dead-ended mode operation II. Under different operation pressures. Energy, 2017, 131: 50-57
    (5)    P.Y. Wang, Z.H. Pu, Y.H. Li, L. Wu, Z.K. Tu, M. Jiang, Z.K. Kou, I. S. Amiinu, S.C. Mu*. Iron-doped nickel phosphide nanosheet arrays: An efficient bifunctional electrocatalyst for water splitting. ACS Applied Materials & Interfaces, 2017, 9 (31), 26001–26007.
    (6)    S.Z. Zhang, B. Chen, P. Shu, M.J. Luo, C.J. Xie, S.H. Quan, Z.K. Tu*, Y. Yi. Evaluation of performance enhancement by condensing the anode moisture in a proton exchange membrane fuel cell stack, Applied Thermal Engineering, 2017, 120: 115-120
    (7)    L. Wu, Z.H. Pu, Z.K. Tu*, I. S. Amiinu, S.J. Liu, P.Y. Wang, S.C Mu*. Integrated design and construction of WP/W nanorod array electrodes toward efficient hydrogen evolution reaction. Chemical Engineering Journal, 2017, 327, 705-712
    (8)    H.W. Chang, Z.M. Wan, X. Chen, S.M. Shu, Z.K. Tu*, S.H. Chan. Energy analysis of a hybrid PEMFC–solar energy residential micro-CCHP system combined with an organic Rankine cycle and vapor compression cycle. Energy Conversion and Management, 2017, 142:374-384
    2016   
    (9)    H.W. Chang, Z.M. Wan, X. Chen, H.N. Zhang, Z.K. Tu*, S.M. Su.  Temperature and humidity effect on aging of silicone rubbers as sealing materials for proton exchange membrane fuel cell applications. Applied Thermal Engineering, 2016, 104: 472-478
    (10)    Z. Pu, X. Ya, I.S. Amiinu, Z.K. Tu*, X Liu, W. Li, S. C. Mu, Ultrasmall tungsten phosphide nanoparticles embedded in nitrogen- doped carbon as a highly active and stable hydrogen-evolution electrocatalyst, Journal of Materials Chemistry A, 2016, 4, 15327-15332
    (11)    B. Chen, J. Wang, T. Yang, Y. Cai, C. Zhang, S.H. Chan, Y. Yu, Z.K. Tu*. Carbon corrosion and performance degradation mechanism in a proton exchange membrane fuel cell with dead-ended anode and cathode. Energy, 2016,106:54-62
    (12)    B. Chen, J. Wang, T. Yang, M. Pan, Z.K. Tu*, C. Zhang, S.H. Chan, Y. Yu. Mitigation studies of carbon corrosion by optimizing the opening size of the cathode outlet in a proton exchange membrane fuel cell with dead-ended anode. Energy Conversion and Management, 2016, 119: 60-66
    (13)    X. Chen, G.C. Gong, Z.M. Wan, C.Z. Zhang, Z.K. Tu. Performance study of a dual power source residential CCHP system based on PEMFC and PTSC. Energy Conversion and Management, 2016, 119: 163-176
    (14)    C.Z. Zhang, T. Yu, J. Yi, Z.T Liu, K. A. R. Raj, L.C Xia, Z.K. Tu, S. H. Chan. Investigation of heating and cooling in a stand-alone high temperature PEM fuel cell system. Energy Conversion and Management, 2016, 129:36-42
    2015
    (15)    B Chen, W Ke, M Luo, J Wang, Z.K. Tu*, M Pan, H Zhang. Operation characteristics and carbon corrosion of PEMFC with dead-ended anode for high hydrogen utilization. Energy, 2015, 91:799-806
    (16)    B. Chen, M.M. Wang, Z.K. Tu*, X. Gong, H.N. Zhang, M. Pan, Y.H. Cai, Z.M. Wan. Moisture Dehumidification and Its Application to a 3kW Proton Exchange Membrane Fuel Cell. International Journal of Hydrogen Energy, 2015, 40(2):1137-1144
    (17)    Z.C. Liu, J. Shen, H.C. Pei, Z.K. Tu*, J. Wang, Z.M. Wan*, W. Liu. Effect of Humidified Water Vapor on Heat Balance Management in a Proton Exchange Membrane Fuel Cell Stack, International Journal of Energy Research, 2015, 39(4):504-515
    (18)    I.S. Amiinu, W. Li, G.J. Wang, Z.K. Tu, H.L. Tang, M. Pan, H.N. Zhang*. Toward Anhydrous Proton Conductivity Based on Imidazole Functionalized Mesoporous Silica/Nafion Composite Membranes. Electrochimica Acta, 2015, 160: 185-194
    2014
    (19)    J. Feng, Q.L. Zhang, Z.K. Tu*, W.M. Tu, Z.M. Wan, M. Pan, H.N. Zhang*, Degradation of silicone rubbers with different hardness in various aqueous solutions, Polymer Degradation and Stability, 2014, 109:122-128
    (20)    W. Li, X.M. Liang, H.F. Niu, Z.K Tu*, J. Feng, M. Pan, H. N. Zhang*. Decorating titanate nanotubes with protonated 1, 2, 4-triazole moieties for anhydrous proton conduction. Journal of Colloid and Interface Science, 2014, 432:26-30
    (21)    Z.K. Tu, H.L. Tang*, X.T. Shen. Particle-Assisted Semidirect Breath Figure Method: A Facile Way to Endow the Honeycomb-Structured Petri Dish with Molecular Recognition Capability. ACS Applied Materials & Interfaces, 2014, 6:12931-12938
    (22)    J. Feng, Y.Q Huang, Z.K. Tu, H.L. Tang, M. Pan, H.N. Zhang*, Proton conduction of polyAMPS brushes on titanate nanotubes, Scientific Reports, 2014, 4:6225  
    (23)    H.C. Pei, J. Shen, Y.H. Cai, Z.K. Tu*, Z.M. Wan, Z.C. Liu, W. Liu. Operation Characteristics of Air-cooled Proton Exchange Membrane Fuel Cell Stacks under Ambient Pressure. Applied Thermal Engineering, 2014, 63:227-233
    (24)    Z.M. Wan, J. Shen, H.N. Zhang, Z.K Tu*, W. Liu. In Situ Temperature Measurement in a 5kW-class Proton Exchange Membrane Fuel Cell Stack with Pure Oxygen as the Oxidant, International Journal of Heat and Mass Transfer, 2014, 75: 231-234
    (25)    D.D. Wang, Z.C. Liu*, J Shen, B.B. Chen, J.G. Yang, Z.K. Tu, W. Liu. Experimental study of the loop heat pipe with a flat disk-shaped evaporator, Experimental Thermal and Fluid Science, 2014, 57: 157-164
    (26)    D.H. Ye, Z.K. Tu*, Y. Yu, H.N. Zhang, Z.G. Zhan, M. Pan. Hydrogen Permeation across Super-thin Membrane and the Burning Limitation in Low-temperature Proton Exchange Membrane Fuel Cell. International Journal of Energy Research, 2014,38: 1181-1191
    (27)    Y.S. Wang, B. Zhou, Z.C. Liu*, Z.K. Tu, W. Liu*. Numerical study and performance analyses of the mini-channel with discrete double-inclined ribs. International Journal of Heat and Mass Transfer, 2014, 78: 498-505
    2013
    (28)    Z.K. Tu, H. N. Zhang*, Z.P. Luo, J. Liu, Z.M. Wan, M. Pan, Evaluation of 5kW Proton Exchange Membrane Fuel Cell Stack Operated at 95oC under Ambient Pressure, Journal of Power Sources, 2013, 222:277-281
    (29)    H.C. Pei, Z.C. Liu, H.N. Zhang, Y. Yu, Z.K. Tu*, Z.M. Wan, W. Liu*, In Situ Measurement of Temperature Distribution in Proton Exchange Membrane Fuel Cell Ⅰ A Hydrogen-Air Stack, Journal of Power Sources, 2013, 227: 72-79
    (30)    Z.M. Wan, J. Liu, Z.P. Luo, Z.K. Tu*, Z.C. Liu, W. Liu, Evaluation of self-water-removal in a dead-ended proton exchange membrane fuel cell, Applied Energy, 2013,104: 751-757
    (31)    C.X. Huang, Z.K. Tu*, X.T. Shen, Molecularly imprinted photocatalyst with a structural analogue of template and its application, Journal of Hazardous Materials, 2013, 248-249: 379-386
    (32)    G.Q. Ding, H.Q. Tang, Z.P. Luo, Z.K. Tu*, H.C. Pei, Z.C. Liu, W. Liu. Water Distribution and Removal along the Flow Channel in Proton Exchange Membrane Fuel Cells. Journal of Wuhan University of Technology-Materials Science Edition, 2013, 28: 243-248
    (33)    F.F. Zhang, Z.K. Tu, J. Yu, H.B. Li, C. Huang, H.N. Zhang*. Impregnation of imidazole functionalized polyhedral oligomeric silsesquioxane in polymer electrolyte membrane for elevated temperature fuel cells, RSC Advances, 2013, 3: 5438-5446
    (34)    I. S. Amiinu, X.M. Liang, Z.K. Tu, H.N. Zhang*, J.W. Feng, Z.M. Wan, M.Pan. Anhydrous Proton Conducting Materials Based on Sulfonated Dimethylphenethylchlorosilane Grafted Mesoporous Silica/Ionic Liquid Composite, ACS Applied Materials & Interfaces, 2013, 5:11535-11543
    (35)    D. H. Ye, Z.G. Zhan*, Y. J. Lee, Z. K. Tu, Y. Zhang, M. Pan*. Effects of Frame Materials and Structures on Stress Concentration of Membrane Electrode Assembly of PEMFCs, Fuel Cells, 2013,13:1205-1212
    2012
    (36)    Z.K. Tu, M. Pan, W. Liu*, Z.C. Liu, Z.M. Wan, Modeling of stability of the condensing interface in a capillary pumped loop,  International Journal of Heat and Mass Transfer, 2012, 55:1709-1715  
    (37)    Y. Yu, Z.K. Tu*, Z.G. Zhan, M. Pan, Gravity effect on the performance of PEM Fuel Cell Stack with different gas inlet/outlet positions,  International Journal of Energy Research, 2012, 36: 845-855
    (38)    Z.M. Wan, J.H. Wan, J. Liu, Z.K. Tu*, M. Pan, Z.C. Liu, W. Liu, Water recovery and air humidification by condensing the moisture in the outlet gas of a proton exchange membrane fuel cell stack, Applied Thermal Engineering, 2012,42:173-178
    (39)    Z.M. Wan, G.Q. Guo, Z.K. Tu*, W. Liu, Experimental analysis of flow and heat transfer in a miniature porous heat sink for high heat flux application, International Journal of Heat and Mass Transfer, 2012, 55: 4437-4441
    (40)    Q. Li, H.N. Zhang*, Z.K. Tu, J. Yu, C.X. Xiong, M. Pan, Impregnation of amine-tailoredtitanate nanotubesinpolymer electrolyte membranes, Journal of Membrane Science, 2012, 423-424: 284-292
    (41)    Y. Yu, G. J. Wang*, Z.K. Tu, Z.G. Zhan, M. Pan, Effect of gas shutoff sequences on the degradation of proton exchange membrane fuel cells with dummy load during startup and shutdown cycles, Electrochimica Acta, 2012, 71:181-193
    Before 2011
    (42)    Y. Yu*, Z.K. Tu, H.N. Zhang, M. Pan. Comparison of degradation behaviors for open-ended and closed proton exchange membrane fuel cells during startup and shutdown cycles. Journal of Power Sources, 196, 5077-5083, 2011
    (43)    Z.M. Wan*, J. Liu, J.H. Wan, Z.K. Tu, W. Liu,  An overall numerical investigation on heat and mass transfer for miniature flat plate capillary pumped loop evaporator, Thermochimica Acta, 518, 82-88, 2011
    (44)    Z.K. Tu, W. Liu*, Z.C. Liu, X.M. Huang, Interface stability in a capillary loop undergoing phase changes in non-gravitational conditions, Chinese Science Bulletin, 55, 4069−4073, 2010
    (45)    W. Liu*, Z.C. Liu, Z.K. Tu, Phase change driving mechanism and modeling for heat pipe with porous wick, Chinese Science Bulletin, 54, 4000-4004, 2009
    (46)    Z.M. Wan*, W. Liu, Z.K. Tu, A. Nakayama, Conjugate numerical analysis of flow and heat transfer with phase change in a miniature flat plate CPL evaporator. International Journal of Heat and Mass Transfer, 52, 422-430, 2009
    (47)    Z.K. Tu, Z.C. Liu, D.X. Gai, Z.M. Wan, W. Liu*, Heat and mass transfer in a flat disc shaped evaporator of a miniature LHP. Proc. IMechE, Journal of Aerospace Engineering, 223, 609-618, 2009
        专利
    (1)    涂正凯,付为国,余意,詹志刚,潘牧. 能够低温保存和低温启动的质子交换膜燃料电池系统,2012.3,发明专利,ZL201110349637.8
    (2)    涂正凯,余意,叶东浩,罗志平,潘牧. 质子交换膜燃料电池自反馈加湿器,2011.11,发明专利,ZL 201110386726.X
    (3)    涂正凯,陈奔,潘牧. 一种圆环形燃料电池双极板,2012.10,发明专利,ZL201210330784
    (4)    涂正凯,陈奔,潘牧. 一种短时封闭式燃料电池,2012.10,发明专利,ZL 201210330801
    (5)    涂正凯,陈奔,叶东浩,潘牧. 一种质子交换膜燃料电池尾气处理装置,2012.10,发明专利,ZL 201210332838

所获荣誉和奖励